Newer Semiconductor Materials.

September 16, 2021 bandgap, cell, cells, DSSC, dye, inorganic, nanoparticles, OPV, organic, perovskite, polymer, PPV, PV, quantum dots, solar, thin-film, titanium dioxide No Comments

Newer Materials.

1. Dye-Sensitized.

Another type of solar cell material is a small molecule dye, such as a ruthenium metalorganic dye, that can absorb a broad range of the visible region of sunlight. An inorganic mesoporous nanoparticle layer, usually titanium dioxide, increases the area for light absorption. Solar cells using these materials can be made using solution processing, making them inexpensive to fabricate.

Dye-sensitized solar cells (DSSCs) belong to the group of thin-film solar cells which have been under extensive research for more than two decades due to their low cost, simple preparation methodology, low toxicity and ease of production.

Still, there is lot of scope for the replacement of current DSSC materials due to their high cost, less abundance, and long-term stability.

2. Organic/Polymer.

Semiconducting polymers such as polyphenylene vinylene (PPV) and small organic small molecules such as phthalocyanines, polyacenes, and squarenes are also used in solar cells. These highly conjugated organic molecules have a broad absorption in the visible and near infrared region. These materials are deposited as thin films either by vacuum deposition methods or solution processing, and solar cells using these materials are usually thin and flexible. However, the efficiency of these cells is still low, just a little more than 10%, hence they have not been commercialized yet.

OPV cells are currently only about half as efficient as crystalline silicon cells and have shorter operating lifetimes, but could be less expensive to manufacture in high volumes.

They can also be applied to a variety of supporting materials, such as flexible plastic, making OPV able to serve a wide variety of uses.

3. Perovskite.

Perovskite cells are generally hybrid organic-inorganic lead or tin-halide materials, such as methylammonium lead halide. The cells are built with layers of materials that are printed, coated, or vacuum-deposited onto an underlying support layer, known as the substrate.

These materials can be solution-processed, hence enable inexpensive and simple fabrication. They are typically easy to assemble and can reach efficiencies similar to crystalline silicon.In the lab, perovskite solar cell efficiencies have improved faster than any other PV material, from 3% in 2009 to over 25% in 2020.

One of the key advantages of these materials is their ability to absorb sunlight across the entire visible spectrum.

To be commercially viable, perovskite PV cells have to become stable enough to survive 20 years outdoors, so researchers are working on making them more durable and developing large-scale, low-cost manufacturing techniques.

4. Quantum dots.

Nanoparticles, a few nm in size, called quantum dots are another type of emerging materials used in solar cells that conduct electricity through tiny particles of different semiconductor materials just a few nanometers wide. They are low bandgap semiconductor materials such as CdS, CdSe, and PbS. Their bandgaps can be tuned over a wide range by changing the size of the particles.

Quantum dots provide a new way to process semiconductor materials, but it is difficult to create an electrical connection between them, so they’re currently not very efficient. However, they are easy to make into solar cells. They can be deposited onto a substrate using a spin-coat method, a spray, or roll-to-roll printers like the ones used to print newspapers.

Many common materials used for fabricating quantum dots such as Cd and Pb are considered toxic, hence other alternative materials such as copper indium selenide are being developed.

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Thin-Film Solar Cell.

September 16, 2021 a-Si, amorphous, Cadmium Telluride, CdTe, cell, cells, CIGS, Copper Indium Gallium Selenide, GaAs, Gallium Arsenide, PV, silicon, solar, thin-film No Comments

Thin-Film.

Thin-film are cells that have light-absorbing layers about 350 times smaller than the standard silicon. Because of their narrow design and the efficient semiconductor built into their cells, thin-film solar cells are the lightest PV cell you can find while still maintaining strong durability.

The cell is made by depositing one or more thin layers of PV material on a supporting material such as glass, plastic, or metal.

Thin-film solar panels are typically made with one of the following four technologies:

• Cadmium Telluride (CdTe) – The most widely used thin-film technology, CdTe holds roughly 50% of the market share for thin-film solar panels. CdTe contains significant amounts of Cadmium – an element with relative toxicity – so this is a factor of consideration. First Solar is the top innovator and seller in this space.

• Amorphous Silicon (a-Si) – The second most popular thin-film option after CdTe, a-Si is the most similar technology to that of a standard silicon wafer panel. a-Si is a much better option than its counterparts (CdTe, CIGS) in terms of toxicity and durability, but it is less efficient and is typically used for small load requirements like consumer electronics. The quest for scale is always a hindrance for a-Si.

• Copper Indium Gallium Selenide (CIGS) – Laboratory CIGS cells have reached efficiency highs of 22.4%. However, these performance metrics are not yet possible at scale. The primary manufacturer of CIGS cells was Solyndra (which went bankrupt in 2011). Today, the leader is Solar Frontier. MiaSolé also manufactures CIGS panels in the U.S. and China.

• Gallium Arsenide (GaAs) – A very expensive technology, GaAs holds a world record 28.9% efficiency for all single-junction solar cells. GaAs is primarily used on spacecrafts and is meant for versatile, mass-scale installments of PV energy in unusual environments.

It is used in building-integrated photovoltaics and as semi-transparent, photovoltaic glazing material that can be laminated onto windows.

Thin film solar panels are the cheapest, but have the lowest efficiency rating and require a lot of space to meet your energy needs

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Silicon - The Most Popular Material for Solar Cells.

September 16, 2021 amorphous, cell, crystalline, monocrystalline, polycrystalline, silicon, solar No Comments

Silicon - The Most Popular Material for Solar Cells.

The basic component of a solar cell is pure silicon, which has been used as an electrical component for decades as the silicon solar cell technology gained ground already in the 1950s.

Pure crystalline silicon is a poor conductor of electricity as it is a semiconductor material at its core. To address this issue, the silicon in a solar cell has impurities-meaning that other atoms are purposefully mixed in with the silicon atoms in order to improve silicon’s ability to capture the sun’s energy and convert it into electricity.

Solar cells made out of silicon currently provide a combination of high efficiency, low cost, and long lifetime. Modules are expected to last for 25 years or more, still producing more than 80% of their original power after this time.

There are mainly three types of Silicon solar cells:

MONOCRYSTALLINE		POLYCRYSTALLINE		AMORPHOUS

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Semiconductor Materials for PV Cells.

September 16, 2021 cell, cells, photovoltaic, semiconductors, silicon, solar No Comments

Semiconductor Materials.

Special materials are used for the construction of photovoltaic cells. These materials are called semiconductors.

In most of today solar cells the absorption of photons, which results in the generation of the charge carriers, and the subsequent separation of the photo-generated charge carriers take place in semiconductor materials.

Therefore, the semiconductor layers are the most important parts of a solar cell; they form the hart of the solar cell. There are a number of different semiconductor materials that are suitable for the conversion of energy of photons into electrical energy, each having advantages and drawbacks.

The most commonly used (by far) for the construction of photovoltaic cells is silicon and the arrival of new materials have been developed recently. In the table below, are showed the different semiconductor materials:

SILICON		THIN-FILM		NEWER MATERIALS

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Solar Photovoltaic Cell (also called a solar cell).

September 15, 2021 amorphous, arrays, cell, cells, crystalline, panels, photovoltaic, polycrystalline, PV, semiconductor, silicon No Comments

Solar cell, also called photovoltaic (PV) cell, any device that directly converts the energy of light into electrical energy through the photovoltaic effect. The PV cell is composed of semiconductor material. Unlike batteries or fuel cells, solar cells do not utilize chemical reactions or require fuel to produce electric power, and, unlike electric generators, they do not have any moving parts.

When the semiconductor is exposed to light, it absorbs the light’s energy and transfers it to negatively charged particles in the material called electrons. This extra energy allows the electrons to flow through the material as an electrical current.

The efficiency of a PV cell is simply the amount of electrical power coming out of the cell compared to the energy from the light shining on it, which indicates how effective the cell is at converting energy from one form to the other.

The overwhelming majority of solar cells are fabricated from silicon, with increasing efficiency and lowering cost as the materials range from amorphous (noncrystalline) to polycrystalline to crystalline (single crystal) silicon forms.

Structure and operation.

Light enters the device through an optical coating, or antireflection layer, that minimizes the loss of light by reflection; it effectively traps the light falling on the solar cell by promoting its transmission to the energy-conversion layers below. The antireflection layer is typically an oxide of silicon, tantalum, or titanium that is formed on the cell surface by spin-coating or a vacuum deposition technique.

The three energy-conversion layers below the antireflection layer are the top junction layer, the absorber layer, which constitutes the core of the device, and the back junction layer. Two additional electrical contact layers are needed to carry the electric current out to an external load and back into the cell, thus completing an electric circuit.

The electrical contact layer on the face of the cell where light enters is generally present in some grid pattern and is composed of a good conductor such as a metal. Since metal blocks light, the grid lines are as thin and widely spaced as is possible without impairing collection of the current produced by the cell. The back electrical contact layer has no such diametrically opposed restrictions. It need simply function as an electrical contact and thus covers the entire back surface of the cell structure. Because the back layer also must be a very good electrical conductor, it is always made of metal.

The amount of electricity produced from PV cells depends on the characteristics (such as intensity and wavelengths) of the light available and multiple performance attributes of the cell.

Solar cells can be arranged into large groupings called arrays. These arrays, composed of many thousands of individual cells, can function as central electric power stations, converting sunlight into electrical energy for distribution to industrial, commercial, and residential users.

Solar cells in much smaller configurations, commonly referred to as solar cell panels or simply solar panels, have been installed by homeowners on their rooftops to replace or augment their conventional electric supply. Solar cell panels also are used to provide electric power in many remote terrestrial locations where conventional electric power sources are either unavailable or prohibitively expensive to install.

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Photovoltaic Solar Technology.

September 15, 2021 arrays, cell, cells, electricity, modules, panel, panels, photovoltaic, polycrystalline, power, PV, silicon, systems No Comments

Solar cells, also called photovoltaic cells, convert sunlight directly into electricity.  Photovoltaics (often shortened as PV) gets its name from the process of converting light (photons) to electricity (voltage), which is called the photovoltaic effect. This material, usually made of silicon but potentially other polycrystalline thin films, generates a direct current when sunlight hits the panel.

A single PV device is known as a cell. An individual PV cell is usually small, typically producing about 1 or 2 watts of power. To boost the power output of PV cells, they are connected together in chains to form larger units known as modules or panels. Modules can be used individually, or several can be connected to form arrays.

Commercially available PV panels are up to 22.5% efficient at converting sunlight into electricity in optimal conditions, but even in partly cloudy weather, they can operate at 80% of their maximum output.

PV systems may or may not be connected to the electric transmission grid:

• PV systems linked to the transmission grid can supplement utilities energy supply during daylight hours, which normally include the peak energy demand periods.
• Independent PV cells can power a variety of individual items, from personal calculators and streetlights to water pumps on ranches and remote settlements far from power lines.

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